2000 - 2001 - 2002 - 2003 -
2004 - 2005 - 2006


Année 2006

"Access to stereodefined trisubstituted alkenes via rhodium-catalyzed 1,4-addition of potassium trifluoro(organo)borates to Baylis-Hillman adducts" L. NAVARRE, S. DARSES, J.P. GENET Adv. Synth. Catal., 2006, 348, 317-322.

"Alkoxy- and Hydroxycyclization of Enynes Catalyzed by Pd(II) and Pt(II) Catalysts" V. MICHELET, L. CHARRUAULT, S. GLADIALI, J.P. GENET Pure & Appl. Chem., 2006, 78, 397-407.

"Oxidative addition of RCO2H and HX to chiral diphosphine complexes of iridium(I): convenient synthesis of mononuclear halo-carboxylato-iridium(III) complexes and cationic dinuclear halogen-triply-bridged iridium(III) complexes and their catalytic performance for asymmetric hydrogenation of cyclic imines and 2-phenylquinoline" T. YAMAGATA, H. TADAOKA, M. NAGATA, T. HIRAO, Y. KATAOKA, K. MASHIMA, V. VIDAL, J.P. GENET Organometallics, 2006, accepté.

"Room Temperature Au(I)-Catalyzed Exo-Selective Cycloisomerization of Acetylenic Acids - An Entry to Functionalized γ-Lactones" E. GENIN, P.Y. TOULLEC, S. ANTONIOTTI, C. BRANCOUR, J.P. GENET, V. MICHELET J. Am. Chem. Soc., 2006, 128, 3112.

"Efficient and green access to functionalized and highly constrained heteropolycyclic derivatives via a microwave accelerated Diels-Alder cycloaddition and heterogeneous hydrogenation sequence" K. KRANJC, M. KOCEVAR, F. IOSIF, S.M. COMAN, V.I. PARVULESCU, E. GENIN, J.P. GENET, V. MICHELET Synlett, 2006, sous presse.

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Année 2005

"First Stereoselective Synthesis of the C(1)-C(13) Fragment of Dolabelides Using Ruthenium-SYNPHOS® Catalyzed Asymmetric Hydrogenation Reactions" R. LE ROUX, N. DESROY, P. PHANSAVATH, J.P. GENET Synlett, 2005, 3, 429-432.

"An overview of synthetic and biological studies of ambruticin and analogues" V. MICHELET, J.P. GENET Curr. Org. Chem., 2005, 9, 405-418.

"An IrI-Catalyzed exo-Selective Tandem Cycloisomerization / Hydroalkoxylation of Bis-homopropargylic Alcohols at Room Temperature" E. GENIN, S. ANTONIOTTI, V. MICHELET, J.P. GENET Angew. Chem. Int. Ed., 2005, 44, 4949-4953.

"Highly Efficient Access to Strained Bicyclic Ketals via Gold-catalyzed Cycloisomerization of Bis-homopropargylic Diols" S. ANTONIOTTI, E. GENIN, V. MICHELET, J.P. GENET J. Am. Chem. Soc., 2005, 127, 9976-9977.

"Potassium trifluoro(organo)borates in rhodium-catalyzed 1,4-additions to α,β-unsaturated esters" L. NAVARRE, M. PUCHEAULT, S. DARSES, J.P. GENET Tetrahedron Lett., 2005, 46, 4247-4250.

"Ru-SYNPHOS® and Ru-DIFLUORPHOS®: highly efficient catalysts for practical preparation of β-hydroxyamides" R. TOUATI, T. GMIZA, S. JEULIN, C. DEPORT, V. RATOVELOMANANA-VIDAL, B. BEN HASSINE, J.P. GENET Synthesis, 2005, 2478-2482.

"Carbinol derivatives via rhodium-catalyzed addition of potassium trifluoro(organo)borates to aldehydes" M. PUCHEAULT, S. DARSES, J.P. GENET Chem. Commun., 2005, 4714-4716.

"Multidrug resistance reversal agent from Jatropha elliptica" B. MARQUEZ, L. NEUVILLE, N.J. MOREAU, J.P. GENET, A. F. DOS SANTOS, M.C. CAÑO DE ANDRADE, A.E. GOULART SANT’ANA Phytochemistry, 2005, 66, 1804-1811.

"Multigram-scale asymmetric hydrogenation reactions using Ru-SYNPHOS® and Ru-DIFLUORPHOS® catalysts" S. JEULIN, N. CHAMPION, P. DELLIS, V. RATOVELOMANANA-VIDAL, J.P. GENET Synlett, 2005, 20, 3666-3671.

"Antibacterial activity of some Brazilian medicinal plants" M.R. FERREIRE de LIMA, J. DE SOUZA LUNA, A.F. DOS SANTOS, M.C. CAÑO DE ANDRADE, A.E. GOULART SANT'ANA, J.P. GENET, B. MARQUEZ, L. NEUVILLE, N.J. MOREAU J. Ethnopharmacol., 2005, sous presse.

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Année 2004

"DIFLUORPHOS®, an electron-poor diphosphane: A good match between electronic and steric features" S. JEULIN, S. DUPRAT DE PAULE, V. RATOVELOMANANA-VIDAL, J.P. GENET, N. CHAMPION, P. DELLIS Angew. Chem. Int. Ed., 2004, 43, 320-325.

"Efficient access to alanines derivatives by 1,4-additions of potassium trifluoro(organo)borates" L. NAVARRE, S. DARSES, J.P. GENET Eur. J. Org. Chem., 2004, 69-73.

"Tandem 1,4-addition/enantioselective protonation catalyzed by rhodium complexes: efficient access to α-amino acids" L. NAVARRE, S. DARSES, J.P. GENET Angew. Chem. Int. Ed., 2004, 43, 719-723.

"An alternative procedure for the synthesis of [5]- and [7]-carbohelicenes" R. EL ABED, B. BEN HASSINE, J.P. GENET, M. GORSANE, A. MARINETTI Eur. J. Org. Chem., 2004, 1517-1522.

"Synthesis of a configurationally locked [5]-helicene derivative" R. EL ABED, B. BEN HASSINE, J.P. GENET, M. GORSANE, J. MADEC, L. RICARD, A. MARINETTI Synthesis, 2004, 15, 2513-2516.

"Chiral biphenyl diphosphines for asymmetric catalysis: stereoelectronic design and industrial perspectives" S. JEULIN, S. DUPRAT DE PAULE, V. RATOVELOMANANA-VIDAL, J.P. GENET, N. CHAMPION, P. DELLIS Proc. Nat. Acad.Sci., 2004, 101, 5799-5804.

"Novel fluorophores: Efficient synthesis and photophysical properties" R. METIVIER, R. AMENGUAL, I. LERAY, V. MICHELET, J.P. GENET Org. Lett., 2004, 6, 739-742.

"Functionalized Carbo- and Heterocycles via Pt-catalyzed Asymmetric Alkoxycyclization of 1,6-enynes" L. CHARRUAULT, V. MICHELET, R. TARAS, S. GLADIALI, J.P. GENET Chem Commun., 2004, 850-851.

"An efficient ruthenium-catalyzed formal synthesis of (-)-isoavenaciolide" O. LABEEUW, D. BLANC, P. PHANSAVATH, V. RATOVELOMANANA-VIDAL, J.P. GENET Eur. J. Org. Chem., 2004, 2352-2358.

"Efficient synthesis of trisubstituted alkenes in an aqueous-organic system using a versatile and recyclable Rh/m-TPPTC catalyst" E. GENIN, V. MICHELET, J.P. GENET Tetrahedron Lett., 2004, 45, 4157-4161.

"Baylis-Hillman adducts in rhodium-catalzyed 1,4-additions: unusual reactivity" L. NAVARRE, S. DARSES, J.P. GENET Chem Commun., 2004, 1108-1109.

"A versatile route to syn and anti α-amino-β-hydroxyesters from β-ketoesters using dynamic kinetic resolution with Ru-SYNPHOS® catalyst" C. MORDANT, P. DUNKELMANN, V. RATOVELOMANANA-VIDAL, J.P. GENET Eur. J. Org. Chem., 2004, 3017-3026.

"Dynamic kinetic resolution: an efficient route to anti α-amino-β-hydroxyesters via Ru-SYNPHOS® catalyzed hydrogenation" C. MORDANT, P. DUNKELMANN, V. RATOVELOMANANA-VIDAL, J.P. GENET Chem Commun., 2004, 1296-1297.

"Efficient access to chiral β-arylamides via asymmetric 1,4-additions of potassium trifluoro(organo)borates" M. PUCHEAULT, V. MICHAUT, S. DARSES, J.P. GENET Tetrahedron Lett., 2004, 45, 4729-4732.

"New developments in the synthesis of heterotopic atropisomeric diphosphines via diastereoselective aryl coupling reactions" J. MADEC, G. MICHAUD, J.P. GENET, A. MARINETTI Tetrahedron: Asymmetry, 2004, 15, 2253-2261.

"Total synthesis of sulfobacin A through dynamic kinetic resolution of racemic β-keto-α-aminoester hydrochloride" O. LABEEUW, P. PHANSAVATH, J.P. GENET Tetrahedron: Asymmetry, 2004, 15, 1899-1908.

"Rh-catalyzed addition of boronic acids to alkynes for the synthesis of trisubstituted alkenes in a biphasic system - Mechanistic study and recycling of the Rh/m-TPPTC catalyst" E. GENIN, V. MICHELET, J.P. GENET J. Organomet. Chem., 2004, 689, 3820-3830.

"Synthesis of new polycyclic β-lactams via one-pot enyne metathesis and diels-alder reactions" N. DESROY, F. ROBERT-PEILLARD, J. TOUEG, C. HENAUT, R. DUBOC, M.N. RAGER, M. SAVIGNAC, J.P. GENET Synthesis, 2004, 16, 2665-2672.

"Synthesis of modified Weinreb amides: N-tert-butoxy-N-methylamides as effective acylating agents" O. LABEEUW, P. PHANSAVATH, J.P. GENET Tetrahedron Lett., 2004, 45, 7107-7110.

"Synthesis of both syn and anti diastereoisomers of Boc-dolaproine from (S)-proline through DKR using ruthenium-catalyzed hydrogenation: a dramatic role of N-protecting groups" C. MORDANT, S. REYMOND, V. RATOVELOMANANA-VIDAL, J.P. GENET Tetrahedron, 2004, 60, 9715-9723.

"An efficient route to 4/5/6 polycyclic β-lactams" N. DESROY, F. ROBERT-PEILLARD, J. TOUEG, R. DUBOC, C. HENAUT, M.N. RAGER, M. SAVIGNAC, J.P. GENET Eur. J. Org. Chem., 2004, 4840-4849.

"Direct access to ketones from aldehydes via rhodium-catalyzed cross-coupling reaction with potassium trifluoro(organo)borates" M. PUCHEAULT, S. DARSES, J.P. GENET J. Am. Chem. Soc., 2004, 126, 15356-15357.

"A novel water-soluble m-TPPTC ligand: steric and electronic features. Recent developments in Pd- and Rh-catalyzed C-C bond formations" E. GENIN, R. AMENGUAL, V. MICHELET, M. SAVIGNAC, A. JUTAND, L. NEUVILLE, J.P. GENET Adv. Synth. Catal., 2004, 346, 1733-1741.

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Année 2003

"An efficient synthesis of diltiazem via dynamic kinetic resolution" C. MORDANT, V. RATOVELOMANANA-VIDAL, B. BEN HASSINE, R. TOUATI, J.P. GENET Synthesis, 2003, 2405.

"SYNPHOS, a new chiral diphosphine ligand: synthesis, molecular modeling and application in asymmetric hydrogenation" S. DUPRAT DE PAULE, S. JEULIN, V. RATOVELOMANANA-VIDAL, J.P. GENET, N. CHAMPION, P. DELLIS Tetrahedron Lett.,2003, 44, 823.

"Enantioselective hydrogenation of a-keto esters using chiral diphosphines-ruthenium complexes: Optimization for academic and industrial purposes and synthetic applications" V. RATOVELOMANANA-VIDAL, C. GIRARD, R. TOUATI, J.P. TRANCHIER, B. BEN HASSINE, J.P. GENET Adv. Synth. Catal. 2003, 345, 261.

"Synthesis of SYNPHOS, a new efficient diphosphine ligand in ruthenium-catalyzed asymmetric hydrogenation and molecular modeling studies" S. DUPRAT DE PAULE, S. JEULIN, V. RATOVELOMANANA-VIDAL, J.P. GENET, N. CHAMPION, P. DELLIS Eur. J. Org. Chem., 2003, 1931.

"On the mechanism of carbohydroxypalladation of enynes. Additional insights on the cyclization of enynes with electrophilic metal complexes" C. NEVADO, L. CHARRUAULT, V. MICHELET, C. NIETO-OBERHUBER, M. PAZ MUÑOZ, M. MÉNDEZ, M.N. RAGER, J.P. GENET, A. M. ECHAVARREN Eur. J. Org. Chem. 2003, 706.

"Stereoselective of C15-C24 and C25-C30 fragments of dolabelides" N. DESROY, R. LE ROUX, P. PHANSAVATH, L. CHIUMMIENTO, C. BONINI, J.P. GENET Tetrahedron Lett. 2003, 44, 1763.

"Remarkable stereocontrol in the synthesis of 1,2,3,5-tetrasubstituted tetrahydropyrans via an asymmetric heterocycloaddition of a ketone-derived enol ether" J. GONG, E. BONFAD, E. BROWN, G. DUJARDIN, V. MICHELET, J.P. GENET Tetrahedron Lett. 2003, 44, 2141.

"Rhodium and ruthenium complexes of 1,1’-bis(phosphetano)ferrocenes: structural characterisations and catalytic behaviour" A. MARINETTI, F. LABRUE, B. PONS, S. JUS, L. RICARD, J.P. GENET Eur. J. Inorg. Chem., 2003.

Revue: "Asymmetric catalytic hydrogenation and synthetic applications" J.P. GENET, Account Chemical Research, 2003.

Revue: "Catalyse homogène et synthèse organique" J.P. GENET Actualité Chimique 2003.

Microrevue: "New perspective in organoboron chemistry" S. DARSES, J.P. GENET  Eur. J. Org. Chem., 2003.

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Année 2002

"Convenient synthesis of new anionic water-soluble phosphanes and applications in inter and intramolecular Heck reactions" R. AMENGUAL, E. GENIN, V. MICHELET, M. SAVIGNAC, J.P. GENET Advanced Synth. Catalysis 2002, 344, 393.

"  Recent studies on asymmetric hydrogenation. New catalysts and synthetic applications in organic synthesis" J.P. GENET Pure Appl. Chem. 2002, 74, 1.

"Palladium cross-coupling reactions on solid support using a new silylated linker" R. DUBOC, M. SAVIGNAC, J.P. GENET J. Organomet. Chem. 2002, 643, 512.

"A strategy for the stereoselective synthesis of unsymmetric atropisomeric ligands: Preparation of NAPhePHOS , a new biaryl diphosphine" G. MICHAUD, M. BULLIARD, J.P. GENET, A. MARINETTI, L. RICARD Chem. Eur. J., 8, 15.

"Pd-catalyzed route to (±)-podophyllotoxin skeleton. Synthesis of the aryltetralin derviative" L. CHARRUAULT, V. MICHELET, J.P. GENET Tetrahedron Letters, 2002, 43, 4457.

"Stereoselective Ru(II)-catalyzed hydrogenation of vinylphosphonic acids, J.P. GENET, V. RATOVELOMANANA-VIDAL, Catalyst for the fine and chemical industry, Vol. 1, Eds Wiley VCH, 2002

"Potassium organotrifluoroborates. New partners in catalytic enantioselective conjugate addition" M. PUCHEAULT, S. DARSES, J.P. GENET Tetrahedron Letters 2002, 43, 6155.

"New studies of Rh-catalyzed addition of boronic acids under basic conditions in aqueous medium" R. Amengual, V. Michelet, GenEt, J.P. Tetrahedron Letters 2002, 43, 5905.

"Synthesis of biologically active 1-arylethylphosphonates" N.S. GULYUKINA, T.M. DOLGINA, G.N. BONDERENKO, I.P. BELETSKAYA, N.A. BONDARENKO, J.C. HENERY, D. LAVERGNE, V. RATOVELOMANANA-VIDAL, J.P. GENET, Russian Journal of Organic Chemistry 2002, 38, 600.

"Synthesis of new 3-substituted-2H-1,2-naphthothiazin-4(3H)-one 1,1-dioxides via directed ortho-metalation reaction" Y. KACEM, A. BOURAOUI, V. RATOVELOMANANA-VIDAL, J.P. GENET, B. BEN HASSINE, C.R. Acad. Sciences Chimie, 2002, 5.

"Potassium organotrifluoroborates in rhodium-catalyzed asymmetric 1,4-additions to enones" M. Pucheault, S. Darses, J.P. Genet, Eur. J. Org. Chem. 2002, 3552.

"A new practical procedure for asymmetric 1,4-addition of boronic acids to a, b-unsaturated ketones catalyzed by Rh-(R)-digm-BINAP system" R. Amengual, V. Michelet, J.P. Genet, Synlett, 2002, 11, 1791.

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Année 2001

" Recent advances in asymmetric catalysis. Synthetic applications to biologically active compounds" A. MARINETTI, J.P. GENET, V. RATOVELOMANANA-VIDAL Pure and Applied Chemistry, 2001, 73, 2.

"Asymmetric hydrogenation reactions using a practical in situ generation of chiral ruthenium-diphosphine catalysts from anhydrous RuCl3" J. MADEC, X. PFISTER, P. PHANSAVATH, V. RATOVELOMANANA-VIDAL, J.P. GENET Tetrahedron, 2001, 57, 2563.

"Efficient access to perfluorinated aryl compounds via Heck reaction" S. DARSES, M. PUCHEAULT, J.P. GENET Eur. J. Org. Chem. 2001, 1128.

"A practical synthetic approach to chiral a-aryl substituted ethylphosphonates" N.S. GOULIOUKINA, T.M. DOLGINA, I.P. BELETSKAYA, J.C. HENRY, D. LAVERGNE, V. RATOVELOMANANA-VIDAL, J.P. GENET Tetrahedron: Asymmetry 2001, 12, 319.

"Synthetic approach to tricyclic b-lactams using a sequential metathesis/Diels-Alder reaction" R. DUBOC, C. HENAUT, M. SAVIGNAC, J.P. GENET, N. BHATNAGAR, Tetrahedron Lett., 2001, 42, 2461.

"First approach to the cycloisodityrosine unit of RA-IV" O. POUPARDIN, F. FERREIRA, J.P. GENET, C. GRECK Tetrahedron Lett. 2001, 42, 1523.

"Recyclable diguanidinium-BINAP and PEG-BINAP supported catalysts:syntheses and use in Rh(I) and Ru(II) asymmetric hydrogenations reactions" P.GUERREIRO, V. Ratovelomanana-Vidal, J.P. GENET, P.DELLIS Tetrahedron Lett.  2001, 42, 3423.

"Efficient metallo-ene reactions in organoaqueous phase" V. MICHELET, J.C. GALLAND, L. CHARRUAULT, M. SAVIGNAC, J.P. GENET Org. Lett., 2001, 3, 13, 2065.

"Stereoselective synthesis of iso-dolaproine via dynamic kinetic resolution" D. LAVERGNE, C. MORDANT, V. Ratovelomanana-Vidal, J.P. GENET Org. Lett., 2001, 3, 12, 1909.

"Direct use of chiral or achiral organophosphorus boranes as pro-ligands for transition metal catalyzed reactions" C. DARCEL, E.B. KALOUN, R. MERDES, D. MOULIN, N. RIEGEL, S. THORIMBERT, J.P. GENET, S. JUGE J. Organomet. Chem., 2001, 624, 333.

"Suzuki cross-coupling of arylboronic acids mediated by a hydrosoluble Pd(0)/TPPTS catalyst" C. Dupuis, K. Adiey, L. Charruault, V. Michelet, M. Savignac, J.P. Genet, Tetrahedron Lett. 2001, 42, 6523.

"Cycloisomerization of 1,6-enynes in organoaqueous medium: an efficient and eco-friendly access to furan derivatives. Synthesis of a key intermediate of podophyllotoxin" J.C. GALLAND, S. DIAS, M. SAVIGNAC, J.P. GENET Tetrahedron, 2001, 57, 5137.

"Synthesis and characterization of monophosphines and aminophosphines bearing chiral phosphetane units" A. MARINETTI, S. JUS, F. LABRUE, A. LEMARCHAND, J.P. GENET, L. RICARD Synthesis 2001, 2095.

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Année 2000

"Additional data on the synthesis and properties of chiral 1,2-bis (phosphetano)benzenes" A. MARINETTI, S. JUS, J.P. GENET, L. RICARD Tetrahedron 2000, 56, 95.

"Enantioselective preparation of 2,4-disubstituted azetidines" A. MARINETTI, P. HUBERT, J.P. GENET Eur. J. Org. Chem. 2000, 1815.

"Heck reactions using aryldiazonium salts towards phosphonic derivatives" H. Brunner, N. Le Cousturier de Courcy, J.P. GENET Synlett 2000, 201

"Asymmetric synthesis of fluorinated b-hydroxy esters via ruthenium-mediated hydrogenation, D. BLANC, V. RATOVELOMANANA-VIDAL, J.P. GILLET, J.P. GENET J. Organomet. Chem. 2000, 603, 128.

"Chiral ruthenium catalyzed hydrogenation of b-keto sulfoxides" S. DUPRAT DE PAULE, L. PIOMBO, V. RATOVELOMANANA-VIDAL, C. GRECK, J.P. GENET Eur. J. Org. Chem. 2000, 1535.

"An efficient formal synthesis of (-)balanol via ruthenium-catalyzed asymmetric hydrogenation" P. PHANSAVATH, S. DUPRAT DE PAULE, V. RATOVELOMANANA-VIDAL, J.P. GENET Eur. J. Org. Chem. 2000, 3903.

"Industrial synthesis of (+)-cis methyl dihydrojasmonate by enantioselective catalytic hydrogenation: Identification of the precatalyst [Ru(-)-Me-Duphos)(H)(h6-1,3,5-cyclooctatriene]BF4" V. RAUTENSTRAUCH, K.P. VANHESSCHE, D.A. DOLLS, E. BRAZZI, J.P. GENET, J.Y. LENOIR, J. WILES, S.H. BERGENS Angew. Chem. Int. Ed. 2000, 112, 1992.

"Synthetic applications to the ruthenium-catalyzed hydrogenations via dynamic kinetic resolution" V. RATOVELOMANANA-VIDAL, J.P. GENET Can. J. Chem., 2000, 78, 846.

"Asymmetric synthesis of hydroxylated pyrrolizidine, indolizidines and (+)-a-conhydrine via ruthenium-catalyzed hydrogenation" P. GUERREIRO, V. RATOVELOMANANA-VIDAL, J.P. GENET Chirality, 2000, 408.

"Synthèse d’imines optiquement pures par la technique micro-onde et application à la préparation de nouvelles amines secondaires" R. TOUATI, B. BEN HASSINE, J.P. GENET C.R. Acad. Sci. Paris 2000, IIc, 3, 35.

"Efficient asymmetric synthesis of functionalized D2-pyrazoline" O. POUPARDIN, C. GRECK, J.P. GENET Tetrahedron Lett., 2000, 41, 8795.

"Chiral 1,2-bis(phosphetano)ethanes" A. MARINETTI, S. JUS, J.P. GENET, L. RICARD J. Organomet. Chem. 2000, 624, 162.

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